It is not advisable to mix different silicon before applied. The approach tank maker used is applied first round of white silicon on primary joint; and subsequently applied the black silicon on fillet & bracing (including the vertical & bottom) which will ensure fast curing of structure. And transfer the entire tank to storage location for full curing.
I think it is not recommended by DC to use DC795 on surfaces that are continuous immersed in water. to use DC 795.
according to their usage ( http://www.dowcorning.com/DataFiles/090007b5801797db.pdf ), Under Limitation, DC stated that the DC 795 is not to be used on surfaces that are continuous immersed in water. So for fish tank that has this silicon used must not have water in it, I guess
good night