However, on the part about the pH going down , IMO it is unlikely because the OH- mainly comes from the Kalk solution that is added. But surely agree with the Ca2+ being wasted as in the ppt(precipitate) form, it is not made available to the corals. Since the marine tank is alkaline, the possibility of the solid carbonate dissolving is low. So as good as not adding.
Sand is a type of silicate and does not contain really contain CaCO3. However, some rocks and corals do contain contains CaCO3.=> not really impt, just feel like saying something