Alkalinity : More Than Meets the Eye
Ask any reefer worth his salt, he will tell you keeping a stable alkalinity in the reef aquarium is of paramount importance. Most reefers soon learn to test, and suppliement alkalinity reasonably well.
However, how does alkalinity influence the activities in the reef? Many reefers will say it helps to build the coral skeleton. This is true, but there are much more important processes requiring alkalinity in the aquarium.
What is Alkalinity
Alkalinity is a system of buffers. A buffer helps a mixture to maintain its pH within a reasonable range. It's like a shield, so to speak. When an acid is added into the seawater, alkalinity (the shield) will wear down first, before pH starts to drop rapidly. Conversely, when an alkaline is added, alkalinity will increase first, until the capacity is exceeded. Then the pH will skyrocket rapidly.
So first thing to remember, alkalinity protects against both downward and upward shift in pH. This is one of the most crucial function of alkalinity in reef.
We can test the alkalinity by the process of titration. We add acid to the water sample until the alkalinity is depleted, and the pH dropped sharply. That's the buffering capacity of the water.
Source of Alkalinity in the Reef
The alkalinity in the reef comes from two different buffer systems: bicarbonate /carbonate buffer and borate buffer. We shall look at these briefly so that we can have a good picture of what's in our sea water.
Firstly, let's talk about borate buffer. Element Boron exists in seawater, but in small quantities (5ppm or so). Therefore the capacity of the borate buffer in a reef aquarium can be as high as 20% of the total buffer capacity. Boron is used by reef animals, but the consumption is rather low. Therefore it's not critical to test boron (no harm though). What we should keep in mind is, the titration reports total alkalinity. This means that the titration tests (salifert, alkatronic, etc) does not report the carbonate hardness (dispite many product says so).
Then, the bicarbonate buffer. Bicarbonate ions are much more abundant (about 150 ppm) in seawater. As such, they are doing most of thr heavy-lifting for the buffer in the sea. The interaction of bicarbonate with the rest of the reef is complex and interesting. I'll spend the next post to discuss it.